The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (N-compounds) / Peroxynitrates / CF3O2NO2 / Malanca(2005)_273K_200-340nm

DATAFILE: CF3O2NO2_Malanca(2005)_273K_200-340nm.txt
NAME: trifluoromethyl peroxynitrate
FORMULA: CF3O2NO2
AUTHOR(YEAR): Malanca(2005)
T: 273K
λ: 200-340nm
BIBLIOGRAPHY: F.E. Malanca, M.S. Chiappero, G.A. Argüello, and T.J. Wallington, "Trifluoro methyl peroxynitrate (CF3OONO2): Temperature dependence of the UV absorption spectrum and atmospheric implications", Atmos. Environ. 39, 5051-5057 (2005); DOI: 10.1016/j.atmosenv.2005.05.026
COMMENTS: Averages over 5-nm intervals of the spectrum recorded at a resolution of 1 nm using a diode array spectrometer.

The representation of log σ vs. T leads to linear fits according to

log10 σ(T) = B × T + log10 σ(0 K).

The intercepts σ(0 K) and slopes B at selected wavelengths are as follows (standard deviations of B in brackets):

---------------------------------------------------
λ  103 B   1020 σ(0 K)
(nm) (K-1)   (cm2 molecule-1)
---------------------------------------------------
290 6.8 (0.2)  1.2×10-2
295 8.3 (0.9)  2.9×10-3
300 10.5 (0.6)   4.4×10-4
305 12 (1)    8.4×10-5
310 14 (1)    1.9×10-6
315 16.4 (0.9)  2.9×10-6
320 18 (2)    6.0×10-7
325 22 (3)    3.7×10-8
330 26 (4)    1.3×10-9

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